Meanwhile, synthesis routes, characterization and calculation methods, as well as electrochemical performances of heterostructures are roundly reviewed. Furthermore, prospects and potential directions of heterojunctions are proposed, aiming to guide the future energy storage.
The features of heterointerfaces are beneficial to the performances of heterojunction anodes in Li + /Na + batteries, in terms of enhanced reaction kinetics, significant pseudocapacitance effects with superior rate property, increased active sites and excellent structural stability.
The research of heterojunctions pays more attention to the effects brought by the intrinsic feature of the building blocks (e. g., band structures, alignment styles, semiconductor types, carrier concentration, and Fermi level difference) on the electronic structure and electric field distribution of whole materials.
In recent years, metal compound-based heterojunctions have received increasing attention from researchers as a candidate anode for lithium/sodium-ion batteries, because heterojunction anodes possess unique interfaces, robust architectures, and synergistic effects, thus promoting Li/Na ions storage and accelerating ions/electrons transport.
Generally, heterojunctions have been widely used in the fields of semiconductor electronics and optoelectronic devices in the past period. Besides, chemical vapor deposition (CVD) and mechanical exfoliation are the classic methods for heterojunction preparation.
This heterojunction interlocked catalysis-conduction network shows unique advantages for the Li 2 S n conversion ( Fig. 7 g). (1) The three-dimensional scaffold constructed by the interlocked nanoclusters and CNTs is stable and can prevent the catalyst failure during long-term cycling.
5 Heterostructure Anodes for Lithium/Sodium-Ion Storage
The features of heterointerfaces are beneficial to the performances of heterojunction anodes in Li + /Na + batteries, in terms of enhanced reaction kinetics, significant pseudocapacitance effects with superior rate property, increased active sites and excellent structural stability. Meanwhile, the current synthesis and characterization methods ...
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Spontaneous Internal Electric Field in Heterojunction Boosts ...
Heterojunctions are a promising class of materials for high-efficiency bifunctional oxygen electrocatalysts in both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). However, the conventional theories fail to explain why many catalysts behave differently in ORR and OER, despite a reversible path (* O 2 ⇋ * OOH⇋ * O⇋ * OH).
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Highly Efficient and Stable Potassium-Doped g-C
2 · The remarkable photocatalytic activity is primarily ascribed to the formation of a type-II heterojunction between K-CN and ZCS QDs, which enhances charge separation and transfer. …
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A bimetallic-activated MnO2 self-assembly electrode …
A bimetallic-activated MnO2 self-assembly electrode with a dual heterojunction structure for high-performance rechargeable zinc-air batteries June 2022 Energy Materials 2(3):200021
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Recent Advances on Heterojunction‐Type Anode Materials for …
Herein, this review presents the recent research progress of heterojunction-type anode materials, focusing on the application of various types of heterojunctions in lithium/sodium-ion batteries. Finally, the heterojunctions introduced in this review are summarized, and their future development is anticipated.
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Heterostructure conductive interface and melt-penetration …
The wide application of high-energy all-solid-state lithium metal batteries (AS-LMBs) is still challenging due to their dendrite growth at anode, high interfacial resistance and …
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Z-Scheme g-C3N4/TiO2 heterojunction for a high …
Under illumination, the battery can be rechargeable for over 1000 hours at 0.05 mA cm −2 with a small polarization gap. The photocathode delivers an ultra-high discharge capacity of 29.7 mA h cm −2 at 0.5 mA cm −2, …
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Highly Efficient and Stable Potassium-Doped g-C
2 · The remarkable photocatalytic activity is primarily ascribed to the formation of a type-II heterojunction between K-CN and ZCS QDs, which enhances charge separation and transfer. This research represents a significant step forward in the design of heterojunction photocatalysts by merging QDs with g-C 3 N 4, offering a highly effective and durable solution for …
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Heterojunction betavoltaic Si14C-Si energy converter
The betavoltaic battery is a device, based on the junction of semiconductor microelectronics and nuclear technologies, that generates electricity by directly utilizing the deposition of energy in the betavoltaic effect in the semiconductor released during the decay of beta-emitting (β-emitting) radioisotopes [1].The specific development of betavoltaic devices …
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Highly polar CoP/Co2P heterojunction composite as efficient …
LiOH-based batteries are more resistant to steam and more practical than Li 2 O 2.The formation/decomposition of LiOH has been considered as a promising alternative pathway for the Li 2 O 2 cycle [22].To generate LiOH discharge products, we constructed CoP/Co 2 P starting from high polarity. As cathode catalyst for Li-air battery, CoP/Co 2 P composite could …
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Theoretical investigation of high-efficiency GaN–Si heterojunction ...
By optimizing the doping concentration and junction depth, a high-efficiency heterojunction betavoltaic microbattery can be achieved. The maximum power is calculated as 22.90 nW/cm 2 using 1 mCi Ni 63 beta source and GaN–Si heterojunction with junction depth of 0.1 μm and doping concentrations of N a = 4 × 10 17 cm −3 and N d = 4 × 10 16 ...
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Highly active nanostructured CoS2/CoS heterojunction …
The polysulfide/iodide flow battery with the graphene felt-CoS2/CoS heterojunction can deliver a high energy efficiency of 84.5% at a current density of 10 mA cm−2, a power density of 86.2 mW cm ...
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Synergistic engineering of heterojunction and surface coating to …
Based on synergistic engineering of heterojunction, surface coating and porous shell-like micromorphology, the synthesized VON@SiO 2 delivers excellent specific capacities …
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Application of ZIF-67/ZIF-8 derived Co3O4/ZnO heterojunction in …
Lithium-sulfur batteries (LSBs) have attracted widespread attention because of their advantages such as high discharge capacity and high energy density. Although LSBs have good development potential, there are still many obstacles, such as poor conductivity, volume expansion etc., especially shuttle effect which seriously limit the application of LSBs. To …
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Constructing heterojunction on N-doped porous carbon …
In this study, the CoP-Co 2 P heterojunction nanoparticles on N-doped porous carbon nanofibers (CoP-Co 2 P/NPCNFs) are designed and prepared as the catalysts to significantly accelerate the catalytic conversion of LiPS, which can effectively inhibit "shuttle effect" of LiPS and uniform lithium deposition.
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Theoretical investigation of high-efficiency GaN–Si …
By optimizing the doping concentration and junction depth, a high-efficiency heterojunction betavoltaic microbattery can be achieved. The maximum power is calculated as 22.90 nW/cm 2 using 1 mCi Ni 63 beta source and GaN–Si …
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Three-Phase-Heterojunction Cu/Cu
Zn–CO 2 batteries are excellent candidates for both electrical energy output and CO 2 utilization, whereas the main challenge is to design electrocatalysts for electrocatalytic CO 2 reduction reactions with high selectivity and low cost. Herein, the three-phase heterojunction Cu-based electrocatalyst (Cu/Cu 2 O-Sb 2 O 3-15) is synthesized and evaluated for highly …
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5 Heterostructure Anodes for Lithium/Sodium-Ion …
The features of heterointerfaces are beneficial to the performances of heterojunction anodes in Li + /Na + batteries, in terms of enhanced reaction kinetics, significant pseudocapacitance effects with …
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Heterojunction interlocked catalysis-conduction network in …
Herein, a novel heterojunction interlocked catalysis-conduction strategy is proposed to prepare monolithic porous-pipe scaffold for LiPS accommodation. Therein the Co terminal of Co/Mo 2 C heterostructure catalyzes the in-situ growth of carbon nanotubes (CNTs).
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Spontaneous Internal Electric Field in Heterojunction Boosts ...
Illustration of the proposed electron-/hole-rich catalytic center theory (e/h-CCT) theory for the electrocatalytic mechanisms for ORR and OER: a) the spontaneous internal electric field in the heterojunctions; b) the electron-/hole-rich centers in heterojunctions obtained from DFT calculations; c) the DOS near Fermi level of Pt, RuO 2, and heterojunction versus vacuum and …
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