The prediction of the energy of batteries in terms of cohesive and aqueous ionization energies is in excellent agreement with experiment. Since the electrical energy released is equal to the reduction in Gibbs energy, which is the hallmark of a spontaneous process, the analysis also explains why specific electrochemical processes occur.
On the manufacturing side it results in the need for higher power density, higher system reliability and improved energy efficiency for battery formation systems. Switching converters are rapidly adopted in battery formation systems that include a PFC stage, an isolated DC-DC stage, and a non-isolated DC-DC stage.
Analyzing the energetics of the overall cell reaction can also provide insights into how commercial batteries work and where their energy is stored. The most widely used household battery is the 1.5 V alkaline battery with zinc and manganese dioxide as the reactants. Six 1.5 V cells are also combined in series to produce a 9 V battery.
As shown in the figure, the direction of current flow is opposite to the direction of electron flow. The battery continues to discharge until one of the electrodes is used up [3, p. 226]. Figure 9.3.3: Charge flow in a charging battery. Figure 9.3.3 illustrates the flow of charges when the battery is charging.
Unlike the battery standard charging procedures, battery formation process begins with a low current, 0.1 C , and variable output voltage which requires the reliable battery formation power supply to provide stable charging and discharging current.
Electrochemical processes in batteries occur in conjunction with a spontaneous reduction in Gibbs free energy resulting from differences in lattice cohesive energies and ionization free energies (in water) of reactants and products, as confirmed quantitatively for many combinations of metals.
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