Currently, stationary energy-storage only accounts for a tiny fraction of the total sales of lead–acid batteries. Indeed the total installed capacity for stationary applications of lead–acid in 2010 (35 MW) was dwarfed by the installed capacity of sodium–sulfur batteries (315 MW), see Figure 13.13.
Lead–acid batteries have been used for energy storage in utility applications for many years but it has only been in recent years that the demand for battery energy storage has increased.
Lead–acid batteries typically have coulombic (Ah) efficiencies of around 85% and energy (Wh) efficiencies of around 70% over most of the SoC range, as determined by the details of design and the duty cycle to which they are exposed. The lower the charge and discharge rates, the higher is the efficiency.
Hydrogen that is generated during the overcharging of lead–acid batteries that are housed in confined spaces may become an explosion risk. This hazard can be avoided by management of the charging process and by good ventilation. 13.4. Environmental Issues The main components of the lead–acid battery are listed in Table 13.1.
This partial state-of-charge (PSoC) operation can be damaging for lead–acid batteries as it leads to irreversible sulfation of the negative plates and methods to overcome this problem have been the subject of intensive development , . Sustainability is one of the most important aspects of any technology and lead batteries are no exception.
It should be noted that the lead–acid cell is able to operate effectively as an energy-storage device by virtue of three critical factors. First, contrary to thermodynamic expectations, the liberation of hydrogen from acids by lead takes place at only a negligible rate, i.e., there is a high hydrogen overpotential.
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Rechargeable Commercialized Voltage Energy density Specific power Cost † Discharge efficiency Self-discharge rate Shelf life Anode Electrolyte Cathode Cutoff Nominal 100% SOC by mass by volume; year V V V MJ/kg (Wh/kg) MJ/L (Wh/L) W/kg Wh/$ ($/kWh) % %/month years Lead–acid: SLA VRLA PbAc Lead: H 2 SO 4: Lead dioxide: Yes 1881 [1] 1.75 [2] 2.1 [2] 2.23–2.32 [2] …
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