Research on Lewis acid-base interaction leads to unique functionalities based on the coordination chemistry, which should be revisited for advancing batteries. In this review, we discuss the Lewis acid-base interaction from the perspective of materials electrochemistry and battery applications.
With the continuous emergence of novel approaches for utilizing the Lewis acid-base pairs to tailor intermolecular chemistry, the versatility and applicability of Lewis acid-base interactions to different fields of electrochemical energy storage will continue to increase.
By employing Lewis acid-base interactions, the interfacial protective layer can homogenize the distribution of lithium-ion flux and immobilize the anions for high tLi, leading to the regular morphology of lithium metal deposition with suppressed dendrites ( Figure 8a,b ).
The fundamental concepts of Lewis acids and bases are first introduced. Then, the related works are summarized from four aspects based on the different functions of Lewis acid-base interactions, including modification of the aqueous electrolyte, SPEs, metal anodes, and cathode materials for batteries ( Figure 1 ).
The Lewis acid-base theory is based on the electron structure and bonding interaction, acting as a useful tool for predicting a large variety of chemical reactions. The development of the Lewis acid-base theory undergoes several stages from the proposal to the quantum mechanics study, as the history shown in Figure 2a.
Electronic devices have become ubiquitous in recent years, leading to ever-increasing demands for cutting-edge energy storage technologies using liquid-based and solid-state batteries.
Perspective on Lewis Acid-Base Interactions in Emerging Batteries
This review will focus on the origin, development, and prospects of applying …
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Metal-organic frameworks Derived frustrated Lewis acid-base …
The Poly(ethylene oxide) (PEO)-based polymer electrolytes exhibit the drawbacks of high crystallinity and low ionic conductivity (<10 −5 S m −1), which significantly restrict their application in solid-state lithium metal batteries.This study presents the bismuth metal-organic frameworks (MOFs) as a PEO-based electrolyte filler, incorporating frustrated …
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Solid-acid-Lewis-base interaction accelerates lithium ion …
In this work, we loaded solid acid upon mesoporous molecular sieves (SBA-15) and applied them to lithium metal battery systems. Mesoporous molecular sieves have very large specific surface area and pores, they are used to provide sufficient active sites and uniform the lithium ion flow [56, 57].The solid acid of sulfated zirconia (ZrO 2 /SO 4 2−, recorded as SZ) …
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Perspective on Lewis Acid-Base Interactions in Emerging Batteries
The covered topics relate to aqueous batteries, lithium-ion batteries, solid-state batteries, alkali metal-sulfur batteries, and alkali metal-oxygen batteries. In this review, the Lewis acid-base theories will be first introduced. Thereafter the application strategies for Lewis acid-base interactions in solid-state and liquid-based batteries ...
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Regulating Lewis Acid–Base Interaction in Poly (ethylene …
When matched with LiFePO 4 cathode and lithium anode, the prepared all-solid-state lithium batteries (ASSLBs) deliver high reversible capacities of 147 mAh g −1 after 500 cycles at a current density of 1C at 60 °C with an outstanding capacity retention of 91.1% and of 131 mAh g −1 after 150 cycles even at 0.1C and 30 °C.
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Perspective on Lewis Acid‐Base Interactions in Emerging Batteries
This review will focus on the origin, development, and prospects of applying Lewis acid‐base interactions for the materials design and mechanism understanding in the advancement of battery materials and chemistries. The covered topics relate to aqueous batteries, lithium‐ion batteries, solid‐state batteries, alkali metal‐sulfur ...
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4.85 V High-Voltage Lithium Ion Battery Enabled by an In-Situ
Elevating the operating voltage of Lithium-ion battery (LIB) is key to …
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Lead Acid Battery vs Lithium Ion: Which Lasts the Longest?
Advantages of Lead Acid over Lithium: Lower upfront cost - Lead acid batteries are cheaper to purchase initially, about 1/2 to 1/3 the price of lithium for the same rated capacity. Easier to install - Lead acid batteries are less complicated to set up than lithium-ion systems. In the end, it comes down to what power purpose you actually ...
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HF Content of Lithium-Ion Battery Electrolyte by Acid-Base …
This application note provides an easy method to determine the hydrofluoric acid (HF) content in a lithium-ion battery electrolyte through acid-base titration with potentiometric indication. By downloading this application package, you will receive a PDF of the application note as well as the required data for the LabX™ titration software method.
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,UIO-66-NH2LOB（12661mAh g -1）、（0.87V）（169）。 ,/LOBs。 ：. Title: Identifying the Role of Lewis-base Sites for the Chemistry in Lithium-Oxygen Batteries. Author: …
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Lead-acid vs Lithium-ion
Even lead-acid batteries contain other chemicals such as sulphuric acid that are poisonous. But the recycling rate for lead-acid batteries is higher than Li batteries. Also, lead-acid batteries are cheaper because of their wide availability. Given that lithium-ion battery contains landfill -safe materials, they are recyclable. Also with a ...
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Perspective on Lewis Acid-Base Interactions in Emerging Batteries
In this review, we discuss the Lewis acid-base interaction from the perspective of materials electrochemistry and battery applications. This review highlights the strategies of applying Lewis acidic and basic chemistry and the mechanism that leads to superior performance in liquid-based batteries and solid-state batteries.
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Lead-acid vs. lithium-ion (10 key differences)
Lead-acid and lithium-ion batteries share the same working principle based on electrochemistry. They store (charge) and release (discharge) electrons (electricity) through electrochemical reactions. Both of them feature the following parts: Two electrodes: Anode (-), and Cathode (+). Electrolyte. Membrane separator. They differ in the material used for each …
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Lewis-basic nitrogen-rich covalent organic frameworks enable …
Supported by Lewis acid-base theory, the Lewis basic nitrogen atoms in N …
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Perspective on Lewis Acid‐Base Interactions in Emerging Batteries
Lewis acid‐base interactions are common in chemical processes presented in …
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,UIO-66-NH2LOB（12661mAh g …
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Perspective on Lewis Acid-Base Interactions in Emerging Batteries
This review will focus on the origin, development, and prospects of applying Lewis acid-base interactions for the materials design and mechanism understanding in the advancement of battery materials and chemistries. The covered topics relate to aqueous batteries, lithium-ion batteries, solid-state batteries, alkali metal-sulfur batteries, and ...
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4.85 V High-Voltage Lithium Ion Battery Enabled by an In-Situ
Herein, we propose and demonstrate a new concept of introducing Lewis acid-base complex as multifunctional electrolyte additive for high-voltage LIBs, which is in-situ formed through the electron accepting-donating reaction between the adopted Lewis acid (fluoroethylene carbonate, FEC) and Lewis base (tris(trimethylsilyl) phosphite ...
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Perspective on Lewis Acid-Base Interactions in …
In this review, we discuss the Lewis acid-base interaction from the perspective of materials electrochemistry and battery applications. This review highlights the strategies of applying Lewis acidic and basic chemistry and the …
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4.85 V High-Voltage Lithium Ion Battery Enabled by an In-Situ
Herein, we propose and demonstrate a new concept of introducing Lewis …
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