The low-temperature performance of Li-S batteries has been enhanced by researchers through the optimization of anode. Xie and Holoubek have introduced Fluorobenzene (FB) and diethyl ether (DEE) into the electrolyte to achieve this improvement. The proposed mechanisms of DEE are shown in Fig. 7 a.
Even decreasing the temperature down to −20 °C, the capacity-retention of 97% is maintained after 130 cycles at 0.33 C, paving the way for the practical application of the low-temperature Li metal battery. The porous structure of MOF itself, as an effective ionic sieve, can selectively extract Li + and provide uniform Li + flux.
Additionally, considering the poor conductivity of elemental sulfur and lithium polysulfides (LiPSs), the complex charging and discharging process, and to date limited studies of low-temperature behavior and performance, the research on high-capacity low-temperature Li-S battery systems is facing multiple challenges.
When it comes to outdoor battery banks, it is not only essential that the batteries are able to perform safely in a wide temperature range, but also that the containers and cabinets are able to withstand a wide range of environments.
Lithium-ion with cobalt Lithium-ion batteries that contain cobalt — including NMC, LMO, NCA and LCO — require that the ambient temperature surrounding the batteries fall within a narrow window to protect the battery’s performance and warranty, with an upper limit of ~75℉.
However, the low-temperature Li metal batteries suffer from dendrite formation and dead Li resulting from uneven Li behaviors of flux with huge desolvation/diffusion barriers, thus leading to short lifespan and safety concern.
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