Electrochemical demonstrations measured under various simulated and practical (integrated with photovoltaic solar panel) conditions highlight the potential for an ultralong battery lifetime. The PVP-I colloid exhibits a dynamic response to the electric field during battery operation.
Solar batteries present an emerging class of devices which enable simultaneous energy conversion and energy storage in one single device. This high level of integration enables new energy storage concepts ranging from short-term solar energy buffers to light-enhanced batteries, thus opening up exciting vistas for decentralized energy storage.
Bifunctional anode heterojunction (BAH) based solar batteries (Figure 3 d) rely on a different light charging mechanism: Upon light absorption, the photoexcited electrons are stored on the bifunctional anode. The hole is then transferred to the cathode via the external circuit.
By performing both light absorption and charge storage, bifunctional materials enable the most recent and highest level of material integration in solar batteries. To conclude, bifunctional materials are the most recent development in solar battery research.
In summary, bifunctional electrodes present the next step of integrated solar battery designs. Only two electrodes are required, since one of the electrodes is capable of effectively performing two functions: light absorption and charge storage.
A similar device has recently also been published for Li–S batteries. (40) To conclude, the family of devices consisting of three electrodes in one enclosure presents a further step toward integration and marks a significant milestone in the solar battery field.
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