A notable fact when integrating solar cells and energy storage devices is the mismatch between them, 8 for example, a battery with a capacity much more higher than what the PV cell can provide per charging cycle.
The two-electrode mode is the most integrated of the approaches because the rear electrode of the solar cell is shared with the SC while reducing materials and increasing the energy density of the device. However, when combining a DSSC and an SC in a two-electrode configuration, 17 the device presented particular issues.
As mentioned before, there is a natural mismatch between solar cells and storage devices. Even if in theory the voltages of both of them are comparable, the system efficiency can be improved by incorporating power electronics units in order to control the storage charging and discharging process.
This critical literature review serves as a guide to understand the characteristics of the approaches followed to integrate photovoltaic devices and storage in one device, shedding light on the improvements required to develop more robust products for a sustainable future.
An example of this kind of devices was explored in Wang et al, 59 where a conventional DSSC was modified substituting the I − /I electrolyte with a lead-organohalide. The device resulted in a dual-function rechargeable solar battery with an overall efficiency close to 7%.
Over the past years, several review papers have explored the combination of solar cells and energy storage in one single component like Xu et al, 5 indicating the features of the proposed approaches for particular applications.
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