1. Introduction Antimony (Sb) has become an attractive choice as anode material for high performance Li-ion batteries (LIBs) and Na-ion batteries (SIBs) due to its low price, high theoretical capacity (660 mA h g −1 ), moderate working voltage (0.8–0.9 V) and unique low puckered-layer structure .
During the course of experiments with Li 4 Ti 5 O 12 /Sb composite anodes, we have found a new class of electroactive materials namely, the family of lithium antimonites (LiSbO 3 and LiSb 3 O 8) which show encouraging results as lithium-ion battery anode with respect to a low intercalation potential and high discharge capacity.
Antimony (Sb) shows high conductivity and reactivity not only with lithium ions, but also with sodium ions due to its unique puckered layer structure; also, it can deliver a high theoretical capacity of 660 mA h g−1 by forming Li3Sb or Na3Sb.
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion and sodium-ion batteries are introduced in detail along with their electrode mechanisms, synthesis, design strategies and electrochemical performance.
An aqueous solution of stoichiometric amounts of lithium nitrate (LiNO 3) and L-alanine (Merck, 99.0%) was mixed with hydrochloride solution of antimony sulfide (Sb 2 S 5 ). The mixture was heated at a temperature of ∼150 °C on a hot plate with constant stirring by a magnetic needle.
We apologise for any inconvenience this might cause and thank you for your patience. Antimony (Sb) shows high conductivity and reactivity not only with lithium ions, but also with sodium ions due to its unique puckered layer structure; also, it can deliver a high theoretical capacity of 660 mA h g −1 by forming Li 3 Sb or Na 3 Sb.
Antimony-based materials as promising anodes for …
Antimony-based materials as promising anodes for rechargeable lithium-ion and sodium-ion batteries. Jun He a, Yaqing Wei a, Tianyou Zhai a and Huiqiao Li * ab a State Key Laboratory of Material Processing and Die & Mould Technology, …
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Antimony (Sb)-Based Anodes for Lithium–Ion Batteries: …
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic conductivities. Recently, there have been …
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Lithium–antimony alloys: Phase diagram, thermodynamic …
The possibility of using antimony and its alloys with various metals as anode material in lithium–ion batteries is discussed. Data on the phase diagram of the lithium–antimony system and on the thermodynamic properties of lithium–antimony alloys and their electrochemic
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Evaluating a Dual‐Ion Battery with an …
In this context, antimony (Sb) represents another interesting candidate material with the theoretical capacity of 660 mAh/g. 25 Similar to phosphorus, antimony alloys and dealloys with lithium at a higher operating …
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Antimony-based intermetallic compounds for lithium …
Recently, antimony (Sb)-based intermetallic compounds have attracted considerable research interests as new candidate anode materials for high-performance lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) …
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Lithium-antimony-lead liquid metal battery for grid-level energy ...
This Li||Sb-Pb battery comprises a liquid lithium negative electrode, a molten salt electrolyte, and a liquid antimony-lead alloy positive electrode, which self-segregate by density into three distinct layers owing to the immiscibility of the contiguous salt and metal phases. The all-liquid construction confers the advantages of higher current ...
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Lithium antimonite: A new class of anode material for lithium-ion battery
During the course of experiments with Li 4 Ti 5 O 12 /Sb composite anodes, we have found a new class of electroactive materials namely, the family of lithium antimonites (LiSbO 3 and LiSb 3 O 8) which show encouraging results as lithium-ion battery anode with respect to a low intercalation potential and high discharge capacity.
Learn More
Antimony (Sb)-Based Anodes for Lithium Ion Batteries
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic...
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Evaluating a Dual‐Ion Battery with an Antimony‐Carbon …
The work explores novel dual-ion batteries that use an antimony-containing anode and a graphitic cathode. The results contribute to the development of new batteries that may involve anode materials incorporating alloying elements.
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Antimony: The Most Important Mineral You Never …
Antimony is a key element in the manufacture of lithium-ion batteries, as mentioned above, but even more crucial is the fact that it is integral to the development of the next-generation liquid ...
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Lithium–antimony–lead liquid metal battery for grid-level …
However, the barrier to widespread adoption of batteries is their high cost. Here we describe a lithium–antimony–lead liquid metal battery that potentially meets the performance specifications for stationary energy storage applications. This Li||Sb–Pb battery comprises a liquid lithium negative electrode, a molten salt electrolyte, and a ...
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Lithium–antimony alloys: Phase diagram, thermodynamic …
Data on the phase diagram of the lithium–antimony system and on the thermodynamic properties of lithium–antimony alloys and their electrochemical behavior in molten and nonaqueous electrolytes are summarized and analyzed. The possibility of using antimony and its alloys with various metals as anode material in lithium–ion batteries is discussed.
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Antimony (Sb)-Based Anodes for Lithium–Ion Batteries: …
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic...
Learn More
Lithium antimonite: A new class of anode material for lithium-ion …
During the course of experiments with Li 4 Ti 5 O 12 /Sb composite anodes, we have found a new class of electroactive materials namely, the family of lithium antimonites …
Learn More
Lithium-Ion Battery
Not only are lithium-ion batteries widely used for consumer electronics and electric vehicles, but they also account for over 80% of the more than 190 gigawatt-hours (GWh) of battery energy storage deployed globally through 2023. However, energy storage for a 100% renewable grid brings in many new challenges that cannot be met by existing battery technologies alone.
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Evaluating a Dual‐Ion Battery with an …
The work explores novel dual-ion batteries that use an antimony-containing anode and a graphitic cathode. The results contribute to the development of new batteries that may involve anode materials incorporating …
Learn More
A first-principles study of 2D antimonene electrodes for Li ion …
Antimony (Sb) has shown great potential as an anode material for rechargeable Lithium ion batteries (LIBs) because of its low price, high specific capacity and moderate working voltage. But it suffers from poor cycling performance due to the large volume expansion during the charge/discharge process. Nano-scale modification is an ...
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Liquid Metal Battery Will Be on the Grid Next Year
The molten calcium-antimony design promises low cost and long life ... A fully installed 100-megawatt, 10-hour grid storage lithium-ion battery systems now costs about $405/kWh, according a ...
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Bulk antimony sulfide with excellent cycle stability as next …
Scientific Reports - Bulk antimony sulfide with excellent cycle stability as next-generation anode for lithium-ion batteries Skip to main content Thank you for visiting nature .
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Antimony Trisulfide with Graphene Oxide Coated Titania
The performance of the Lithium Ion Batteries (LiBs) is significantly influenced with the synergetic chemical properties of two different materials in a composite form. The specific capacity of both titanium dioxide arrays (TNAs) and Antimony trisulfide (Sb2S3) bottleneck the performance of LiB due to the low conductivity after the implantation as anode material. …
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Antimony-based materials as promising anodes for …
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion …
Learn More
Antimony (Sb)-Based Anodes for Lithium–Ion Batteries: Recent …
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic...
Learn More
Antimony (Sb)-Based Anodes for Lithium–Ion Batteries: Recent …
From this point of view, antimony acts as a promising material because it has good theoretical capacity, high volumetric capacity, good reactivity with lithium and good electronic conductivities. Recently, there have been many works that focused on the development of antimony as an alternative anode.
Learn More
A first-principles study of 2D antimonene electrodes for Li ion …
Antimony (Sb) has shown great potential as an anode material for rechargeable Lithium ion batteries (LIBs) because of its low price, high specific capacity and …
Learn More
Antimony-based intermetallic compounds for lithium-ion and …
Recently, antimony (Sb)-based intermetallic compounds have attracted considerable research interests as new candidate anode materials for high-performance lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to their high theoretical capacity and suitable operating voltage.
Learn More
Antimony-based materials as promising anodes for rechargeable lithium ...
In this study, the recent progress of Sb-based materials including elemental Sb nano-structures, intermetallic Sb alloys and Sb chalcogenides for lithium-ion and sodium-ion batteries are introduced in detail along with their electrode mechanisms, synthesis, design strategies and electrochemical performance. This review aims to present a full ...
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