Low-cost hole transport layer (HTL)-free carbon-based perovskite solar cells (C-PSCs) have drawn considerable interest owing to their simple manufacturing process and excellent stability. However, the insufficient interfacial charge transport severely limits the efficiency of HTL-free C-PSCs.
Finally, an efficiency of 19.89% is achieved for the planar carbon-based perovskite solar cells without a hole transport layer. Article subjects are automatically applied from the ACS Subject Taxonomy and describe the scientific concepts and themes of the article.
In the past ten years, perovskite solar cells (PSCs) have achieved tremendous success, with the efficiency rivalling that of conventional silicon-based devices. To promote commercialization, lowering the production cost and reducing the complexity of the process would make the devices more competitive and thus are highly required.
Perovskite solar cells have made significant progress in the development process in the last decade or so. Lead-based perovskite () solar cells (MA is organic methylammonium cation ( )) were firstly proposed in 2009 with a PCE of 3.8%, and in the last two years have reached 25.5%, and they are still under continuous development.
The planar triple-layer hole transport layer (HTL)-free carbon-based perovskite solar cells (C-PSCs) have outstanding advantages of low cost and high stability, but are limited by low efficiency. The formation of a 3D/2D heterojunction has been widely proven to enhance device performance.
In contrast, the exciton in the perovskite material is Wannier-type with a binding energy of about 50 meV , , thus the photo-excited carriers can be dealt with the same manner with inorganic, which enables us to apply an existed device simulator widely used in inorganic solar cells to the PSCs.
Stable Electron-Transport-Layer-Free Perovskite Solar Cells with …
Here, we report a strategy to fabricate stable ETL-free FAPbI 3 PSCs by in situ formation of a low dimensional perovskite layer between the FTO and the perovskite. This interlayer gives rise to the energy band bending and reduced defect density in the perovskite film and indirect contact and improved energy level alignment between ...
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Carrier Transport Layer-Free Perovskite Solar Cells
Carrier Transport Layer-Free Perovskite Solar Cells. Dr. Liang Wang, Corresponding Author. Dr. Liang Wang [email protected] Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka, Japan. These authors contributed equally to this work. Search for more papers by …
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Hole transport layer-free carbon-based perovskite solar cells with …
Low-cost hole transport layer (HTL)-free carbon-based perovskite solar cells (C-PSCs) have drawn considerable interest owing to their simple manufacturing process and …
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Electron transport layer-free planar perovskite solar cells: Further ...
Device modeling of CH 3 NH 3 PbI 3−x Cl x based electron transport layer-free planar perovskite solar cells was performed. The simulation was conducted by the program …
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20.1 % Certified Efficiency of Planar Hole Transport Layer‐Free …
Comprehensively, the 2D perovskite formed by tetradecylammonium cations achieves the optimal balance of defect passivation, interface charge separation, and charge transport. The planar HTL-free C-PSCs exhibit a new record efficiency of 20.40 % (certified 20.1 %). The authors declare no conflict of interest.
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Highly efficient inverted hole-transport-layer-free perovskite solar cells
To date, the efficiency of inverted HTL-free PSCs has surpassed 20%, and 90% of the initial efficiency can be retained after 1000 h of continuous illumination, showing their great application potential. In this mini-review, we summarize the development …
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Pb/Sn-Based Perovskite Heterojunction for Hole Transport Layer-Free ...
The construction of heterojunctions has been proven to be effective in optimizing the interface energy structure and passivating defect states in perovskite solar cells (PSCs). Tin (Sn)-based perovskites have been demonstrated to have good hole extraction capability and are promising candidates to form heterojunctions with Pb-based ...
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Cost-Effective High-Performance Charge-Carrier-Transport-Layer-Free ...
Perovskite solar cells (PSCs) without charge-carrier-transport layers (CTLs) are theoretically achievable due to the ambipolar charge-carrier-transfer characteristics presenting in perovskites. However, the power conversion efficiency …
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Hole-Transport Layer-Free Tin-Based Perovskite Solar Cells: …
In this work, we propose a tin-based perovskite solar cell with an ETL (Electron Transport Layer) structure of a novel electron transport layer material. We simulated the …
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Hole Transport Layer‐Free Low‐Bandgap Perovskite Solar Cells …
The best-performing LBG PSC with a power conversion efficiency (PCE) of 22.50% and an impressive V OC of 0.911 V is realized, enabling all-perovskite TSCs with an efficiency of 26.03%. The taurine-based HTL-free TSCs have highly increased stability, retaining more than 90% and 80% of their initial PCEs after constant operation under ...
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Broadband absorption enhancement in hole-transport-layer-free ...
Recently, the hole transport layer-free planar perovskite solar cells (HTL-free PSCs) have attracted intense attention. However, the poor absorption of light in the wavelengths longer than 800 nm is an important challenge in all configurations of PSCs. In this study, the HTL-free PSC with a gold rectangular grating at back contact is proposed. In order to improve the …
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Highly efficient, hole transport layer (HTL)-free perovskite solar cell ...
Perovskite solar cells (PSCs) have generated a lot of interest in the scientific horizon due to their high-power conversion efficiency (PCE) and low cost. In the current study, we assessed the photovoltaic efficiency of Li-doped electron transport layer (ETL) PSCs through parameter variation in the absorber layer, electron transport layer (ETL), and ETL-absorber …
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20.1 % Certified Efficiency of Planar Hole Transport …
Comprehensively, the 2D perovskite formed by tetradecylammonium cations achieves the optimal balance of defect passivation, interface charge separation, and charge transport. The planar HTL-free C …
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Highly efficient inverted hole-transport-layer-free …
To date, the efficiency of inverted HTL-free PSCs has surpassed 20%, and 90% of the initial efficiency can be retained after 1000 h of continuous illumination, showing their great application potential. In this mini-review, we summarize …
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High-Efficiency Electron Transport Layer-Free …
The primary purpose of recent research has been to achieve a higher power conversion efficiency (PCE) with stable characteristics, either through experimental studies or through modeling and simulation. In this …
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Pb/Sn-Based Perovskite Heterojunction for Hole Transport Layer …
The construction of heterojunctions has been proven to be effective in optimizing the interface energy structure and passivating defect states in perovskite solar cells (PSCs). …
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Regulating strain in perovskite thin films through charge-transport layers
The power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) have increased from 3.8% 1 to a certified 25.2% 2, approaching those of crystalline silicon solar cells ntinued progress ...
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Cost-Effective High-Performance Charge-Carrier …
Perovskite solar cells (PSCs) without charge-carrier-transport layers (CTLs) are theoretically achievable due to the ambipolar charge-carrier-transfer characteristics presenting in perovskites. However, the power …
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Perovskite hetero-bilayer for efficient charge-transport-layer-free ...
In this work, we propose an ultrathick solution-processed FAPbI 3 (FA: formamidinium)/MAPbI 3 (MA: methylammonium) bilayer for efficient solar cells without TLs, which only consists of two perovskites sandwiched between two electrodes.
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Electron transport layer-free planar perovskite solar cells: …
Device modeling of CH 3 NH 3 PbI 3−x Cl x based electron transport layer-free planar perovskite solar cells was performed. The simulation was conducted by the program SCAPS (Solar Cell Capacitance Simulator). With appropriate physical parameters, a high open-circuit voltage of 1.04
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Perovskite hetero-bilayer for efficient charge-transport-layer-free ...
In this work, we propose an ultrathick solution-processed FAPbI 3 (FA: formamidinium)/MAPbI 3 (MA: methylammonium) bilayer for efficient solar cells without TLs, …
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A detailed review of perovskite solar cells: Introduction, working ...
The perovskite solar cell devices are made of an active layer stacked between ultrathin carrier transport materials, such as a hole transport layer (HTL) and an electron transport layer (ETL). The band alignment depends on their energy level, electron affinity, and ionization potential. The ultra-thin layers with low electron affinities and ionization potential serve as hole …
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Recent review on electron transport layers in perovskite solar cells ...
To unlock the full capability of perovskite, developments to the neighbouring layers play immense roles in the ultimate performance of a perovskite solar device. Here, a brief review comprising of the advancements and roles of electron transport layers (ETLs) is discussed. In addition, the effects of ETL on the charge transport, hysteresis, and stability of perovskite …
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ITO and electron transport layer-free planar perovskite solar cells …
Here, we reported on planar perovskite solar cells (PSCs) which are free of the indium tin oxide (ITO) and electron transport layer (ETL) directly prepared on Nb-doped TiO 2-x (NTO) electrodes. By rapid thermal annealing of NTO film at a temperature of 600 °C under vacuum ambient, we obtained conductive anatase NTO electrodes that act as transparent …
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Carrier transport layer free perovskite solar cell for enhancing …
The recently developed perovskite solar cell (PSC) has revolutionized photovoltaic technology due to the impressive growth in its efficiency. For the sake of enhancing the power conversion efficiency (PCE), the photo absorber-free layer is stacked in between the best suitable carrier transportation layers (CTLs).
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Journal of Materials Chemistry A
Carbon electrodes have gained widespread attention as a sustainable, stable, and low-cost alternative to metal electrodes in perovskite solar cells (PSCs). However, the power conversion efficiency (PCE) of carbon electrode-based PSCs (C-PSCs) without the hole-transport-layer (HTL) lags far behind their metal Journal of Materials Chemistry A HOT Papers
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Hole transport layer-free carbon-based perovskite solar cells …
Low-cost hole transport layer (HTL)-free carbon-based perovskite solar cells (C-PSCs) have drawn considerable interest owing to their simple manufacturing process and excellent stability. However, the insufficient interfacial charge transport severely limits the efficiency of HTL-free C-PSCs.
Learn More