The bio-inspired battery demonstrated excellent dynamic capacity stability over 35 electrochemical and 11,000 bending cycles, as shown by the discharge capacity and coulombic efficiency of the cell when in unbent, positive bend and negative bend states (Fig. 7h).
Despite the huge potential of mechanically flexible batteries in healthcare, robotics, transportation and sensing, their development towards real-world applications is stalled due to issues such as capacity decay, limited energy/power density at any given pliability, compromised safety and poor packaging.
However, for ultra-FBs, newer techniques such as electrospinning and micropatterning need to be established within the battery industry. Similarly, nanocarbon additives such as CNTs/graphene and electrolytes including ILs and solid electrolytes should be optimised for large scale integration.
Under 100% applied strain, the full cell achieved 83.5 mAh g −1 capacity at 0.5 A g −1 cycling rate and the capacity of the cell was largely retained when subjected to varying bending angles (0, 45, 90 and 180°) (Fig. 7e). Fig. 7: Examples of electrode flexibility via shape optimisation.
Zhang, Z. et al. Porous Si decorated on MXene as free-standing anodes for lithium-ion batteries with enhanced diffusion properties and mechanical stability. Chem. Eng. J. 451, 138785 (2023). Hager, M. D. et al. Polymer-based batteries-flexible and thin energy storage systems. Adv. Mater. 32, e2000587 (2020).
The anode demonstrated an initial capacity of 1579.6 mAh g −1 and dropping to 643.3 mAh g −1 (retained) after 500 cycles at 1000 mA g −1 (Fig. 3o), where the graphene structure appeared to help accommodating volume expansion of Si (~300%).
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