Since little is known about the influence of different end groups on inverted PSCs, various terminal groups have been employed for the systematic evaluation of their performance in fabricated solar cell. The synthesis of target structures was proved by NMR analysis.
The effect of synthesized SAM molecules on surface characteristics such as wettability and perovskite formation and also on photovoltaic performance of fabricated solar cells was examined.
Meanwhile, the IPSCs show high compatibility with the flexible substrate for portable or wearable electronic devices and also can be integrated with silicon solar cells for the construction of tandem solar cells to further improve the efficiency of photovoltaics , , , , , .
The numerous defect-induced non-radiative recombination losses and residual stress in the preparation of perovskite film greatly hinder the further improvement of the efficiency and stability of flexible perovskite solar cells (PSCs).
The main structures of proposed molecules have been enriched by flanking thiophene spacer groups to obtain a better conjugation. Since little is known about the influence of different end groups on inverted PSCs, various terminal groups have been employed for the systematic evaluation of their performance in fabricated solar cell.
There is some evidence that interfaces play crucial role in improving solar cell parameters such as open circuit voltage (V OC), short circuit current density (J SC), fill factor (FF) and morphology problems in absorber layer [10, 18, 22].
Effect of functional groups of self assembled monolayer molecules …
The effect of synthesized SAM molecules on surface characteristics such as wettability and perovskite formation and also on photovoltaic performance of fabricated solar …
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Significant Efficiency and Stability Enhancement of …
Combined with the multifunctional effects of ATB, the target flexible and rigid PSCs with ATB modification yield remarkable photoelectric conversion efficiency (PCE) of 21.08% and 23.79%, respectively. More …
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Modulating Acceptor Phase Leads to 19.59% Efficiency Organic Solar Cells
2 · 1 Introduction. Nonfullerene acceptors (NFAs), valued for their narrow bandgap, strong near-infrared absorption, and low energy disorder, have driven significant enhancements in the power conversion efficiency (PCE) of organic solar cells (OSCs), achieving PCEs over 20% in both single-junction and tandem configurations.
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CF3-Functionalized Side Chains in Nonfullerene Acceptors …
The advent of next-generation nonfullerene acceptors (NFAs) has propelled major advances in organic solar cells (OSCs). Here we report an NFA design incorporating …
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Functional cellulose paper with high transparency, high haze, and …
In recent years, the adverse effects of fossil fuel consumption have raised significant concerns [1,2,3,4,5].Perovskite solar cells (PSCs) have emerged as a standout technology due to their high efficiency and low cost [6, 7].At present, the highest certified energy conversion efficiency (PCE) of single-junction PSCs is close to the Shockley-Queisser limit …
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Functional layers in efficient and stable inverted tin-based …
Perovskite solar cells (PSCs) are promising among various photovoltaic technologies due to their high efficiencies, low costs, and simple preparation routes. Owing to the lead toxicity issue in lead-based PSCs, tin (Sn)-based …
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Steering perovskite precursor solutions for multijunction ...
3 · Multijunction photovoltaics (PVs) are gaining prominence owing to their superior capability of achieving power conversion efficiencies (PCEs) beyond the radiative limit of single-junction cells1-8 ...
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Charge-transfer electronic states in organic solar cells
Liu, T., Cheung, D. L. & Troisi, A. Structural variability and dynamics of the P3HT/PCBM interface and its effects on the electronic structure and the charge-transfer rates in solar cells. Phys. Chem.
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Significant Efficiency and Stability Enhancement of Flexible …
Combined with the multifunctional effects of ATB, the target flexible and rigid PSCs with ATB modification yield remarkable photoelectric conversion efficiency (PCE) of 21.08% and 23.79%, respectively. More importantly, the ATB-modified flexible device exhibits outstanding stability and retains 87.3% and 91.6% of the original ...
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Functional layers in efficient and stable inverted tin …
Tin-based perovskite solar cells (TPSCs) have been developing rapidly. Functional layers in inverted TPSCs have strong effects on device performance. This article reviews recent progress of functional layers in …
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Interfacial Passivation for Perovskite Solar Cells: The Effects of ...
Defect passivation is an effective method to improve the performance of perovskite solar cells. In this study, four phenethylammonium iodide featured with different functional groups directly ...
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Recent review of interfacial engineering for perovskite solar cells ...
The structure of PSCs includes a heterojunction device comprising a perovskite active layer, a charge transport layer (CTL), and an electrode [4, 5].The first PSCs were studied using MAPbI 3, a perovskite, which is a light-absorbing material for dye-sensitized solar cells, instead of organic dyes.PSCs can be divided into three structures based on the direction of …
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Effects of introducing functional groups on the performance of ...
Dye-sensitized solar cells (DSSCs) have attracted considerable attention as promising alternatives to conventional inorganic solar devices since Grätzel et al. reported on ruthenium (Ru)-based photosensitizers in 1991 and their high efficiency and low-cost fabrication [1].Typical DSSCs consist of a dye-coated nanoporous semiconductor film as the anode …
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Effect of functional groups of self assembled monolayer …
The effect of synthesized SAM molecules on surface characteristics such as wettability and perovskite formation and also on photovoltaic performance of fabricated solar cells was examined. The carboxylic acid is preferred as an attaching group as it is proper building block to form molecular self-assemblies on metallic surface by means of ...
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Interfacial Passivation for Perovskite Solar Cells: The Effects of the ...
DOI: 10.1021/acsenergylett.9b02375 Corpus ID: 210233346; Interfacial Passivation for Perovskite Solar Cells: The Effects of the Functional Group in Phenethylammonium Iodide @article{Jing2019InterfacialPF, title={Interfacial Passivation for Perovskite Solar Cells: The Effects of the Functional Group in Phenethylammonium Iodide}, …
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Enhancing the Performance of Perovskite Solar Cells …
Here, we use fluorine atom (−F) and methoxy (−OCH 3) functional groups to modify the same molecular fragment, obtaining three kinds of IPMs named YZ-301, YZ-302, and YZ-303, respectively. Through the subtle …
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Recent Developments in Atomic Layer Deposition of Functional
Over the last decade, research in organic–inorganic lead halide perovskite solar cells (PSCs) has gathered unprecedented momentum, putting the technology on the brink of full-scale commercialization. A wide range of strategies have been implemented for enhancing the power conversion efficiency of devices and modules, as well as improving stability toward high …
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Steering perovskite precursor solutions for multijunction ...
3 · Multijunction photovoltaics (PVs) are gaining prominence owing to their superior capability of achieving power conversion efficiencies (PCEs) beyond the radiative limit of …
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Fabrication of Functional Materials for Dye-sensitized Solar Cells
In this article, we review the fabrication of various functional materials and their effects on DSSC performance. Introduction. Dye-sensitized solar cells (DSSCs) represent promising molecular architecture opportunities in the field of energy conversion. DSSCs consist of three crucial parts: a working electrode (WE) with a photosensitizer, an electrolytic mediator, …
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Synergistic effects of the physical modification and chemical ...
Inverted perovskite solar cells (IPSCs) with poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) as hole transport materials exhibit superior stability and low-temperature processibility. However, the hydrophobicity of PTAA renders it difficult to prepare high-quality perovskite films due to the low wettability of perovskite precursor ...
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Enhancing the Performance of Perovskite Solar Cells via the Functional …
Here, we use fluorine atom (−F) and methoxy (−OCH 3) functional groups to modify the same molecular fragment, obtaining three kinds of IPMs named YZ-301, YZ-302, and YZ-303, respectively. Through the subtle combination of −F and −OCH 3, the fragment in YZ-302 exhibits an enhanced electronegativity, rendering the correlative ...
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Comprehensive performance analysis of perovskite solar cells …
Perovskite solar cells (PSCs) have shown high optical absorption and consequently provide high conversion efficiency with stable performance. In our work, CH3NH3PbI3 (MAPbI3) as an absorber layer is analyzed for different crystalline structures. Cubic, tetragonal, and orthorhombic phases of perovskite material are investigated to check the …
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Modulating Acceptor Phase Leads to 19.59% Efficiency Organic …
2 · 1 Introduction. Nonfullerene acceptors (NFAs), valued for their narrow bandgap, strong near-infrared absorption, and low energy disorder, have driven significant enhancements in …
Learn More
Functional layers in efficient and stable inverted tin-based …
Perovskite solar cells (PSCs) are promising among various photovoltaic technologies due to their high efficiencies, low costs, and simple preparation routes. Owing to …
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Effect of functional groups in passivating materials on stability and ...
Post-treatment of formamidinium lead triiodide (FAPbI 3) with ammonium halogen salts, such as phenethylammonium or octylammonium iodide, has been widely used …
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Effect of functional groups in passivating materials on stability …
Post-treatment of formamidinium lead triiodide (FAPbI 3) with ammonium halogen salts, such as phenethylammonium or octylammonium iodide, has been widely used to improve the photovoltaic performance and stability of perovskite solar cells (PSCs) via surface defect passivation.
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Applications of Current Density Functional Theory …
DFT methods in polymer solar cells. The density-functional theory (DFT) has proven massively popular among the massive panel of current theoretical techniques. This success is mainly because no changeable inputs …
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CF3-Functionalized Side Chains in Nonfullerene Acceptors …
The advent of next-generation nonfullerene acceptors (NFAs) has propelled major advances in organic solar cells (OSCs). Here we report an NFA design incorporating CF3-terminated side chains having varying N-(CH2)n-CF3 linker lengths (n = 1, 2, and 3) which introduce new intermolecular interactions, hence strong modulation of the photovoltaic …
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Functional layers in efficient and stable inverted tin-based …
Tin-based perovskite solar cells (TPSCs) have been developing rapidly. Functional layers in inverted TPSCs have strong effects on device performance. This article reviews recent progress of functional layers in inverted TPSCs.
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