This work opens up new avenues for developing efficient and durable lithium metal batteries. Dielectric materials capable of generating a counteracting electric field at the interface to diminish electric field gradients show promise in facilitating uniform lithium deposition and preventing dendrite formation in lithium metal batteries.
In advanced polymer-based solid-state lithium-ion batteries, gel polymer electrolytes have been used, which is a combination of both solid and polymeric electrolytes. The use of these electrolytes enhanced the battery performance and generated potential up to 5 V.
Lithium metal with its high theoretical capacity and low negative potential is considered one of the most important candidates to raise the energy density of all-solid-state batteries. However, lithium filament growth and its induced solid electrolyte decomposition pose severe challenges to realize a long cycle life.
We investigate the impact of the magnitude of the dielectric constant by comparing BaTiO3 (BTO) with Al 2 O 3 (AO) particles that have a dielectric constant of ε r = 4000 and 8, respectively. As such, the dielectric constant of AO only slightly exceeds that of the Li 6 PS 5 Cl (LPSC) solid electrolyte ( ε r = 5).
For example, in situ X-ray tomography provides direct evidence that lithium dendrites/filaments tend to grow along with the grains and grain boundaries of the inorganic solid-state electrolyte [, , ], demonstrating that inhomogeneous lithium metal deposition causes short-circuiting even in solid-state batteries [ 13, 16 ].
Lithium-ion batteries are viable due to their high energy density and cyclic properties. Different electrolytes (water-in-salt, polymer based, ionic liquid based) improve efficiency of lithium ion batteries. Among all other electrolytes, gel polymer electrolyte has high stability and conductivity.
Dielectric LiNbO3 electrolyte regulating internal electric field in ...
The LiNbO3 significantly enhances the internal electric field of NPC along the LiNbO3 particles and establishes uniform interfacial electric field between NPC and electrodes, which …
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Electrolytes in Lithium-Ion Batteries: Advancements in the Era of ...
Different electrolytes (water-in-salt, polymer based, ionic liquid based) improve efficiency of lithium ion batteries. Among all other electrolytes, gel polymer electrolyte has high stability and conductivity. Lithium-ion battery technology is viable due to its high energy density and cyclic abilities.
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Reversible Li plating regulation on graphite anode through a …
Lithium-ion batteries ... we conduct electrochemical evaluations on high-loading LFP//graphite full cells. The active materials loading for the LFP cathode is 15.5 mg cm −2, while that for the graphite anode is 7.5 mg cm −2. Fig. 6 a presents the cyclic voltammetry (CV) curves for the high-loading LFP//graphite full cells with a dielectric BS/BC separator and a conventional PP …
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High dielectric filler for all-solid-state lithium metal battery
Here, dendrite growth in solid-state Li metal batteries is alleviated by introducing a high dielectric material, barium titanate, as a filler that removes the electric field gradients that catalyze dendrite formation.
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Electrolytes in Lithium-Ion Batteries: Advancements in the Era of ...
Different electrolytes (water-in-salt, polymer based, ionic liquid based) improve efficiency of lithium ion batteries. Among all other electrolytes, gel polymer electrolyte has high …
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A composite dielectric membrane with low dielectric loss for …
Dielectric materials capable of generating a counteracting electric field at the interface to diminish electric field gradients show promise in facilitating uniform lithium deposition and preventing dendrite formation in lithium metal batteries. However, the significant obstacle is achieving a balance betwee Journal of Materials ...
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A composite dielectric membrane with low dielectric …
Dielectric materials capable of generating a counteracting electric field at the interface to diminish electric field gradients show promise in facilitating uniform lithium deposition and preventing dendrite formation in …
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Giant dielectric ceramic of Li
Herein, we find that the giant dielectric ceramic of Li0.3Ti0.02Ni0.68O (LTNO) with ultra-high dielectric constant can greatly promote the dissociation of Li salt to generate …
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High dielectric single-ion conducting interphase enables fast …
Herein, we propose a dielectric, single-ion-conductive artificial SEI (DS-SEI) to enable fast-charging Li metal batteries by incorporating Li-Nafion polymer with BTO nanoceramics (Fig. 1 …
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Dielectric LiNbO3 electrolyte regulating internal electric field in ...
A dielectric electrolyte composite with high lithium-ion conductivity for high-voltage solid-state lithium metal batteries. Nat Nanotechnol, 2023, 18: 602–610 . Article CAS PubMed Google Scholar Li NW, Shi Y, Yin YX, et al. A flexible solid electrolyte interphase layer for long-life lithium metal anodes. Angew Chem Int Ed, 2018, 57: 1505–1509. Article CAS Google Scholar Liang …
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A dielectric electrolyte composite with high lithium-ion ...
The LiNi0.8Co0.1Mn0.1O2/PVBL/Li solid-state batteries stably cycle 1,500 times at a current density of 180 mA g−1, and pouch batteries also exhibit an excellent …
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Dielectric LiNbO3 electrolyte regulating internal electric field in ...
The LiNbO3 significantly enhances the internal electric field of NPC along the LiNbO3 particles and establishes uniform interfacial electric field between NPC and electrodes, which fundamentally facilitates the Li-ion transport, weakens the space-charge layer and inhibits the growth of Li dendrites. Continuous fast ion-conducting channels with ...
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(PDF) Structure, dielectric, and temperature-dependent …
The lithium-ion diffusion kinetics on the Li2FeSiO4/C at different temperatures (− 5 to 400 °C) has been investigated. Rietveld refinement of the XRD data ensured that the Li2FeSiO4/C possess ...
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A dielectric electrolyte composite with high lithium-ion ...
The LiNi0.8Co0.1Mn0.1O2/PVBL/Li solid-state batteries stably cycle 1,500 times at a current density of 180 mA g−1, and pouch batteries also exhibit an excellent electrochemical and safety ...
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High dielectric single-ion conducting interphase enables fast …
Herein, we propose a dielectric, single-ion-conductive artificial SEI (DS-SEI) to enable fast-charging Li metal batteries by incorporating Li-Nafion polymer with BTO nanoceramics (Fig. 1 a). The Li-Nafion, with its elastic F-rich components, stabilizes the Li metal and facilitates fast, single Li + conduction.
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Giant dielectric ceramic of Li0.3Ti0.02Ni0.68O with abundant …
Schnell J, Günther T, Knoche T, Vieider C, Köhler L, Just A et al (2018) All-solid-state lithium-ion and lithium metal batteries-paving the way to large-scale production. J Power Sources 382:160–175. Article Google Scholar Manthiram A, Yu X, Wang S (2017) Lithium battery chemistries enabled by solid-state electrolytes. Nat Rev Mater 2(4):16103
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High dielectric barium titanate porous scaffold for efficient Li …
Applying operando solid-state nuclear magnetic resonance measurements, we demonstrate that the high dielectric BaTiO 3 porous scaffold promotes dense Li deposition, improves the average...
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(PDF) Structure, dielectric, and temperature-dependent conductivity ...
The lithium-ion diffusion kinetics on the Li2FeSiO4/C at different temperatures (− 5 to 400 °C) has been investigated. Rietveld refinement of the XRD data ensured that the Li2FeSiO4/C possess ...
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Recent advances in lithium-ion battery materials for improved ...
There are different types of anode materials that are widely used in lithium ion batteries nowadays, such as lithium, silicon, graphite, intermetallic or lithium-alloying materials [34]. Generally, anode materials contain energy storage capability, chemical and physical characteristics which are very essential properties depend on size, shape as well as the …
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Giant dielectric ceramic of Li
Herein, we find that the giant dielectric ceramic of Li0.3Ti0.02Ni0.68O (LTNO) with ultra-high dielectric constant can greatly promote the dissociation of Li salt to generate abundant movable Li-ions and realize a high room-temperature ionic conductivity (4.09 × 10–4 S cm−1) as well as a low activation energy (0.16 eV). The ...
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Cathode materials for rechargeable lithium batteries: Recent …
Among various energy storage devices, lithium-ion batteries (LIBs) has been considered as the most promising green and rechargeable alternative power sources to date, and recently dictate the rechargeable battery market segment owing to their high open circuit voltage, high capacity and energy density, long cycle life, high power and efficiency and eco …
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Polymers
Ionic Materials if focused on developing a unique class of High Dielectric Polymers (HDP) designed to enhance functional movement of ions in advanced lithium-ion cells, including Solid-State. High Dielectric Permittivity – high polarity side groups; Low Glass Transition Temp (Tg) – fast segmental relaxation; High Oxidative Stability
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Lithium-ion battery performance improvement using two-dimensional materials
The 2D materials have started to perform a crucial role in improving battery performance in the nanostructuring electrode of lithium-ion batteries. Owing to short Li diffusion pathway and the plentiful adsorption sites in two-dimensional materials, which are advantageous for quick charge mechanisms, they have attracted considerable interest and have interesting …
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Structure, dielectric, and temperature-dependent conductivity …
The transition metal oxides LiMO 2 (M = Co, Ni, and Mn), spinel compounds (LiMn 2 O 4), and olivine compounds (LiMPO 4 (M = Fe, Ni, Co, and Mn)) are the existing promising cathode materials for lithium-ion batteries . These conventional materials have several limitations such as high toxicity, expensive, low theoretical capacity, etc. .
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High dielectric barium titanate porous scaffold for efficient Li …
Applying operando solid-state nuclear magnetic resonance measurements, we demonstrate that the high dielectric BaTiO 3 porous scaffold promotes dense Li deposition, …
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Structure, dielectric, and temperature-dependent conductivity …
The transition metal oxides LiMO 2 (M = Co, Ni, and Mn), spinel compounds (LiMn 2 O 4), and olivine compounds (LiMPO 4 (M = Fe, Ni, Co, and Mn)) are the existing …
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