Provided by the Springer Nature SharedIt content-sharing initiative Nickel-rich layered oxides are one of the most promising positive electrode active materials for high-energy Li-ion batteries.
Hence, different TMD-based materials have been introduced such as MoS 2, CoS 2, TiSe 2, Ni 3 S 2, etc. to be used for electrode materials. In this way, nickel-based materials are promising for batteries due to their easy accessibility .
This review gives an account of the various emerging high-voltage positive electrode materials that have the potential to satisfy these requirements either in the short or long term, including nickel-rich layered oxides, lithium-rich layered oxides, high-voltage spinel oxides, and high-voltage polyanionic compounds.
Accordingly, numerous active materials based on Ni foam have been developed for lithium-based batteries during the last decades and as exhibited in Fig. 1 a, more than 500 papers were published in 2013 and the number of citations is as high as 28,200. Also, the acceptable nickel foam must have some critical parameters which are shown in Fig. 1 b.
In this way, nickel-based materials are promising for batteries due to their easy accessibility . Thus, nickel sulfide such as Ni 3 S 2 could be a suitable cathode material for lithium-based batteries due to its chemical stability sufficient compatibility with organic solvents, and promising electrochemical features [115, 116].
This relationship can be correlated to the change in unit cell volume during the lithiation–delithiation process. This work suggests a universal failure mechanism for Ni-rich positive electrode materials that must be overcome. To access this article, please review the available access options below.
High energy density and lofty thermal stability nickel-rich materials ...
Ni-rich LiNi0.8Mn0.1Co0.1O2 (NCM811) is one of the most promising electrode materials for Lithium-ion batteries (LIBs). However, its instability at potentials higher than 4.3 V hinders its use in LIBs. To overcome this barrier, we have prepared a core–shell material composed of a core of NCM811 (R-3m) and a monoclinic (C2/m) Li2MnO3 shell. The structure …
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Noninvasive rejuvenation strategy of nickel-rich layered positive ...
Herein, we propose an economical and facile rejuvenation strategy by employing the magneto-electrochemical synergistic activation targeting the positive electrode …
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Recent progresses on nickel-rich layered oxide positive electrode ...
In a variety of circumstances closely associated with the energy density of the battery, positive electrode material is known as a crucial one to be tackled. Among all kinds of materials for lithium-ion batteries, nickel-rich layered oxides have the merit of high specific capacity compared to LiCoO 2, LiMn 2 O 4 and LiFePO 4. They have already ...
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An Unavoidable Challenge for Ni-Rich Positive …
Half-cell cycling data collected from 26 sets of Ni-rich materials with different compositions allow a relationship between capacity retention and accessible capacity to be observed. This relationship can be correlated to the …
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Exploring a Co-Free, Li-Rich Layered Oxide with Low Content of Nickel …
Li-rich transition-metal-layered oxides (LRLOs) are a promising class of materials to use as high-capacity/high-potential positive electrodes in LIBs thanks to the large lithium content (e.g., ∼1.2 Li equiv per formula unit) and the exploitation of multiple redox …
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Noninvasive rejuvenation strategy of nickel-rich layered positive ...
Herein, we propose an economical and facile rejuvenation strategy by employing the magneto-electrochemical synergistic activation targeting the positive electrode in assembled Li-ion...
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Nickel Metaphosphate as a Conversion Positive Electrode for Lithium…
Lithium storage schemes based on conversion chemistry have been used in a large variety of negative electrodes achieving capacities 2–3 times higher than graphite. However, to date, relatively few positive electrode examples have been reported. Here, we report a new conversion positive electrode, Ni(PO
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Effects of Fluorine Doping on Nickel-Rich Positive …
LiNiO 2 (LNO), NCA and Nickel-rich NMC cathodes are presently those used in the highest energy density lithium-ion cells but can suffer from insufficient cycle life and poor thermal stability. 1–10 Doping LNO with cations …
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Synthesis of Co-Free Ni-Rich Single Crystal Positive Electrode ...
Synthesis of Co-Free Ni-Rich Single Crystal Positive Electrode Materials for Lithium Ion Batteries: Part I. Two-Step Lithiation Method for Al- or Mg-Doped LiNiO2, Aaron Liu, Ning Zhang, Jamie E. Stark, Phillip Arab, Hongyang Li, J. R. Dahn
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High energy density and lofty thermal stability nickel-rich materials ...
Nickel-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) with layered crystal structure is regarded as a promising positive electrode material for lithium-ion batteries...
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Recent advances in lithium-ion battery materials for improved ...
Johnson et al. discovered a high voltage and very effective cathodic material in 1998, such as lithium rich nickel-manganese ... In order to increase the surface area of the positive electrodes and the battery capacity, he used nanophosphate particles with a diameter of less than 100 nm. This enables the electrode surface to have more contact with the electrolyte …
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Nickel complex based electrodes for Li-ion batteries
This work focuses on the development of nickel-based quinone complexes as electrode materials for next-generation rechargeable batteries. These complexes were …
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Nickel complex based electrodes for Li-ion batteries
This work focuses on the development of nickel-based quinone complexes as electrode materials for next-generation rechargeable batteries. These complexes were synthesized with different substituents and their potential as anode materials in lithium-based systems was investigated. Scanning electron microscopy (SEM) and energy-dispersive X-ray ...
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High energy density and lofty thermal stability nickel-rich materials ...
Ni-rich LiNi0.8Mn0.1Co0.1O2 (NCM811) is one of the most promising electrode materials for Lithium-ion batteries (LIBs). However, its instability at potentials higher than 4.3 V …
Learn More
High energy density and lofty thermal stability nickel-rich materials ...
Ni-rich LiNi0.8Mn0.1Co0.1O2 (NCM811) is one of the most promising electrode materials for Lithium-ion batteries (LIBs). However, its instability at potentials higher than 4.3 V hinders its use in LIBs. To overcome this barrier, we have prepared a core–shell material composed of a core of NCM811 (R-3m) and a monoclinic (C2/m ...
Learn More
An Unavoidable Challenge for Ni-Rich Positive Electrode Materials …
Half-cell cycling data collected from 26 sets of Ni-rich materials with different compositions allow a relationship between capacity retention and accessible capacity to be observed. This relationship can be correlated to the change in unit cell volume during the lithiation–delithiation process.
Learn More
Recent advances of electrode materials based on nickel foam …
Thus, nickel sulfide such as Ni 3 S 2 could be a suitable cathode material for lithium-based batteries due to its chemical stability sufficient compatibility with organic …
Learn More
Review—Advancements in Synthesis Methods for Nickel-Rich …
The positive electrode materials researched and developed for lithium-ion batteries must reconcile the following characteristics: a good capacity for intercalation of ions, a high work potential (extraction/insertion potential of ions) which determines the electromotive force of the system and its energy, a highly specific surface for efficient and reversible insertion of …
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Nickel Metaphosphate as a Conversion Positive …
Lithium storage schemes based on conversion chemistry have been used in a large variety of negative electrodes achieving capacities 2–3 times higher than graphite. However, to date, relatively few positive electrode …
Learn More
Recent advances of electrode materials based on nickel foam …
Thus, nickel sulfide such as Ni 3 S 2 could be a suitable cathode material for lithium-based batteries due to its chemical stability sufficient compatibility with organic solvents, and promising electrochemical features [115, 116].
Learn More
Accelerating the transition to cobalt-free batteries: a hybrid model ...
The positive electrode of a lithium-ion battery (LIB) is the most expensive component 1 of the cell, accounting for more than 50% of the total cell production cost 2.Out of the various cathode ...
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Electrode Materials for Lithium-ion Batteries | SpringerLink
Lithium-ion batteries represent the top of technology in electrical storage devices. Lithium-ion batteries with LiCoO 2 cathode and carbon anode were introduced by SONY in early 1990s [].High-energy density, high power, and long service life make lithium-ion batteries suitable for several applications from mobile phones to laptops and power tools.
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