The polymeric backbone as well as the conducting and binding materials (multi-walled carbon nanotubes and PVDF, respectively) revealed no significant influence on the electrochemical behavior and, as a consequence, the polymers were employed as active material in a composite electrode for lithium organic batteries.
Polymer-based batteries, including metal/polymer electrode combinations, should be distinguished from metal-polymer batteries, such as a lithium polymer battery, which most often involve a polymeric electrolyte, as opposed to polymeric active materials. Organic polymers can be processed at relatively low temperatures, lowering costs.
Among the well-developed, small organic molecules are widely used as organic electrode materials, but usually show poor cycling performance due to the dissolution of active materials. The organic polymers could effectively overcome the dissolution issue of organic compounds in electrolytes, leading to better battery performances.
In summary, polymers are omnipresent in modern day commercial batteries and in battery research activities. One important component of batteries is the separator. While porous separators have been commercially available for a long time, gel–polymer electrolytes and solid polymer electrolytes are emerging areas for lithium-ion battery technology.
The functional benefits of natural biopolymers in batteries are undeniable and have been extensively reviewed in the literature. [6, 15, 16] Overall, these naturally derived polymers are characterized by abundant functional groups that have the ability to dissociate lithium salts and increase ionic conductivity and ion transference number.
None of the above-mentioned batteries would work without polymers. Polymers can be found in the electrodes, where they act as binders, ensuring a good adhesion and contact among the different materials. Furthermore, many membranes are based on polymers.
MODULAR DESIGN OF LI-ION & LI-POLYMER BATTERIES FOR
Adapted from: White, D. A. 2009. "Modular Design of Li-Ion and Li-Polymer Batteries for Undersea Environments". Marine Technology Society Journal. 43(5):xx-yy Page 1 of 27 12/17/2009 MODULAR DESIGN OF LI-ION & LI-POLYMER BATTERIES FOR UNDERSEA ENVIRONMENTS1 David A. White Southwest Electronic Energy Group
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